Measurement and mathematical modeling of solubility of buttery-odor substance (acetoin) in supercritical CO_2 at several pressures and temperatures

摘要

The solubilities of acetoin (3-hydroxy-2-butanone), a frequently used buttery-odor compound in supercritical carbon dioxide (SC-CO_2) at several pressures and temperatures were measured in this work. The measurements were conducted in a static-analytic mode at several pressures ranging from 8MPa to 28MPa and four temperatures of 313.15K, 323.15K, 333.15K, and 343.15K. The equilibrium was established for 3-4h. The solubilities of acetoin in SC-CO_2 increased with increasing both pressure and temperature beyond the crossover pressure at 8MPa. Two density-based models namely Chrastil and Del Valle-Aguilera and Peng-Robinson equation of state (PR-EOS) with quadratic and Stryjek-Vera mixing rules were used to represent experimental solubilities and to describe phase behavior of the system. Both Chrastil and Del Valle-Aguilera models were able to correlate experimental solubility data satisfactorily with absolute average relative deviation (AARD) of 0.27%. Similarly, the phase equilibrium behavior of acetoin+supercritical CO_2 binary system can be well interpreted by PR-EOS with quadratic (AARD of 0.11%) and Stryjek-Vera mixing rules (AARD of 0.08%).