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Density, surface tension and viscosity of liquid binary Al-Zn and ternary Al-Li-Zn alloys

机译:液态二元Al-Zn和三元Al-Li-Zn合金的密度,表面张力和粘度

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Three thermophysical properties: density, surface tension and viscosity of liquid binary Al-Zn and ternary Al-Li-Zn alloys have been investigated in this work, by means of the draining crucible method. Three Al-Li-Zn compositions corresponding to distinguished intermetallic phases, i.e. Al5Li3Zn, Al35Li32Zn33 and AILiZn(3), have been selected for investigation. Experimentally determined surface tension of ternaries has been compared to the modelled one, using the commonly known Butler's model and two sets of ternary interaction parameters given in the literature. Whereas, viscosity calculations for the ternary Al-Li-Zn alloys have been performed using three thermodynamics-based models, selected for their reliability, and confronted to the experimental data measured in this work. Both, measured and modelled surface tension decreased with increasing Li and Zn content, opposite to viscosities exhibiting an increase with Li and Zn content raise. Whereas measured densities of the investigated ternaries are decreasing with Li and Zn content growth in confrontation to the three respective Al-Zn binaries investigated in this work. (C) 2016 Elsevier B.V. All rights reserved.
机译:通过排空坩埚法研究了液态二元Al-Zn和三元Al-Li-Zn合金的三种热物理性质:密度,表面张力和粘度。已选择了三种分别对应于不同的金属间相的Al-Li-Zn成分进行研究:Al5Li3Zn,Al35Li32Zn33和AILiZn(3)。实验中确定的三元表面张力已与建模的三元表面张力进行了比较,使用了众所周知的巴特勒模型和文献中给出的两组三元相互作用参数。而三元Al-Li-Zn合金的粘度计算已使用三个基于热力学的模型进行了选择,这些模型是根据其可靠性进行选择的,并且要面对这项工作中测得的实验数据。随着Li和Zn含量的增加,测量和建模的表面张力均降低,而随着Li和Zn含量的增加,粘度也随之增加。与此相对,在本研究中,与所研究的三个Al-Zn二元化合物相对的情况下,随着Li和Zn含量的增加,所测三元化合物的测量密度逐渐降低。 (C)2016 Elsevier B.V.保留所有权利。

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