Polyester Metallisation with Electroless Silver Plating Process

摘要

In this paper, electroless silver plating process for polyester was reported. The electroless silver plating is basically divided into four stages including pre-cleaning, sensitisation, electroless silver deposition and post-treatment As the electroless silver plating stage is the key stage in affecting the brilliant appearance and various functional properties such as conductivity and ultra-violet protection, we will study the effect of process variables, i.e. amount of silver nitrate (AgNO3), concentration of ammonium hydroxide (NH4OH), concentration of sodium hydroxide (NaOH) and process temperature, using increased amount of silver in fabric surface as an indicator, for optimising the electroless silver plating process for possible industrial application. Experimental results revealed that amount of silver nitrate (AgNO3)=1.77 × 10~(-3) mole; concentration of ammonium hydroxide (NH4OH)=6.25 %; concentration of sodium hydroxide (NaOH)=0.008 g/m/ and process temperature=25 °C can give the best electroless silver plating for polyester fabric. The surface characteristics of the electroless silver-plated polyester fabric were evaluated by scanning electron microscope, X-ray photoelectron spectroscopy and X-ray diffraction analysis. Meanwhile, the performance properties of the electroless silver-plated polyester fabric were measured by CIE L~*, a~* and h~* values, conductivity as well as ultraviolet protection. The experimental results would be discussed thoroughly in this paper.