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Physical ageing of silicate glasses

机译:硅酸盐玻璃的物理老化

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The presented review has been devoted to the problem of volume-determined properties relaxation of silicate glasses at room temperature. It is shown that the experimental data are described by the simple Debye exponential law or by a superposition of two exponents. Their parameters are calculated and systematized. A molecular-kinetic model is proposed for these ageing processes. It proceeds from the possibility of volume relaxation due to the cooperative beta-relaxation mechanism with no change in the system's topology. The characteristic ageing times can be calculated according to equations obtained based on the viscosity data in the glass transition range. The precision of the calculations is about (+-)15% at the time variations from a new weeks up to about 15 years. The system of calculated parameter is proposed which characterizes the completeness of ageing and its rate at any glass age. Optical and thermometric glasses have been ranked by their tendency to ageing. The scheme of future investigations predetermined by practice is defined.
机译:提出的综述致力于室温下硅酸盐玻璃的体积确定的特性松弛问题。结果表明,实验数据通过简单的德拜指数定律或两个指数的叠加来描述。他们的参数被计算和系统化。提出了针对这些老化过程的分子动力学模型。它来自于由于合作的beta松弛机制而导致的体积松弛的可能性,而系统的拓扑结构却没有变化。可以根据基于玻璃化转变范围内的粘度数据获得的方程式来计算特征老化时间。从新的几周到大约15年的时间变化,计算的精度约为(+-)15%。提出了计算参数的系统,该系统表征了在任何玻璃年龄下的时效完整性及其速率。光学和测温玻璃已根据其老化趋势进行了排名。定义了由实践预先确定的未来调查方案。

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