Geochemical analyses on bituminous carbonate reservoir in Alberta, Canada: Focusing on the GC/GC-MS results of bitumen

摘要

The geochemical study on bituminous carbonate reservoir in Alberta has been performed to document the organic geochemical characteristics of the Grosmont Formation using two drilling cores (SAL 03-34 and SAL 08-01), especially focusing on the GC and GC-MS analyses. The results of GC and GC-MS analyses for the extracted organic matter (EOM) showed that all samples have been severely undergone a biodegradation process. However, the GC-MS data have displayed a little variation among the samples, which may be due to degree/type of biodegradation and the type of microbial activity. Triterpane biomarkers are present in low amounts, and steranes in even lesser amounts. Source and maturity assessments from both biomarkers are limited due to the lack of peaks by advanced biodegradation. The demethylated hopanes, which are typical of biodegraded oils, are not seen in these samples but they are apparently not unusual for the Athabasca tar sands, probably due to the specific type of post-emplacement microbial activity. Triterpanes biomarkers illustrate that a highly anoxic hypersaline source environment has contributed to the original oils, at the same time having anoxic marine carbonate/marl character. There is also tenuous evidence for a post-Triassic source according to the tricyclic terpane ratios. The steranes similarly indicate a marine, possibly carbonate-influenced source. Some of the aromatic compounds could also indicate a marine and anoxic hypersaline sourcing. The available peak ratios and patterns of EOM by GC-MS suggest high maturity, and aromatic parameters infer condensate window level with a vitrinite reflectance equivalent range of ～0.9-1.2%. This could explain the remaining relatively light n-alkanes in the saturated GC chromatograms.