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Influence of the corrosion and encrustation of steel casing on the chemical properties of groundwater in wells

机译:钢套管腐蚀与结垢对井中地下水化学性质的影响

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摘要

Temperature, specific electrical conductivity (E), pH, Eh, concentrations of dissolved gases (O_2 and H_2S), and Na~+ activity were measured in situ by means of hydrogeochemical logging. These data showed that the interaction of fresh groundwater and steel pipes in the well space resulted in water demineralization by 10-60% and the formation of a vertical redox zoning. At the top of the well, meteoric oxygen penetrates to a depth of up to 20 m and produces an oxidizing weakly acidic and neutral environment, which is changed with increasing depth by reducing alkalic one (pH 9.2-11.2). The pH-Eh conditions of water in contact with the casing are controlled by the products of corrosion and encrustation and depend on the duration of the contact. The majorcomponent composition and physicochemical properties of groundwater were strongly modified in the filter zones of 20 observation wells. A method is proposed for the derivation of undisturbed hydrogeochemical information on the basis of the measurement of aqueous environment parameters after in situ controlled short-term pumping.
机译:温度,比电导率(E),pH,Eh,溶解气体(O_2和H_2S)的浓度以及Na〜+活性通过水文地球化学测井法现场测量。这些数据表明,井眼空间中的新鲜地下水和钢管之间的相互作用导致水软化率达到10-60%,并形成了垂直氧化还原带。在井的顶部,大气中的氧气渗透到最深20 m,并产生氧化性弱酸性和中性的环境,通过降低碱金属(pH值9.2-11.2),深度会随着变化而变化。与壳体接触的水的pH-Eh条件受腐蚀和结壳产物的控制,并取决于接触的持续时间。在20口观测井的滤区中,地下水的主要成分组成和理化特性发生了很大变化。在现场控制短期抽水后,基于对水环境参数的测量,提出了一种不受干扰的水文地球化学信息的推导方法。

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