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首页> 外文期刊>Geochimica et Cosmochimica Acta: Journal of the Geochemical Society and the Meteoritical Society >Geochemical constraints on depth of origin of oceanic carbonatites: The Cape Verde case
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Geochemical constraints on depth of origin of oceanic carbonatites: The Cape Verde case

机译:地球化学限制海洋碳酸盐岩成因的深度:佛得角案例

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摘要

We present new Sr-Nd isotope compositions together with major- and trace element concentrations measured for whole rocks and mineral separate phases (apatite, biotite and calcite) from fifteen Cape Verde oceanic carbonatites (Atlantic Ocean). Trace element patterns of calcio- and magnesio-carbonatites present a strong depletion in K, Hf, Zr and Ti and an overall enrichment in Sr and REE relative to Cape Verde basalts, arguing for distinct source components between carbonatites and basalts. Sr and Nd isotopic ratios show small, but significant variations defining a binary mixing between a depleted end-member with unradiogenic Sr and radiogenic Nd values and a "enriched" end-member compatible with old marine carbonates. We interpret the depleted end-member as the Cape Verde oceanic lithosphere by comparison with previous studies on Cape Verde basalts. We thus propose that oceanic carbonatites are resulting from the interaction of a deep rooted mantle plume carrying a lower ~4He/~3He signature from the lower mantle and a carbonated metasomatized lithosphere, which by low degree melting produced carbonatite magmas. Sr-Nd compositions and trace element patterns of carbonatites argue in favor of a metasomatic agent originating from partial melting of recycled, carbonated oceanic crust. We have successfully reproduced the main geochemical features of this model using a Monte-Carlo-type simulation.
机译:我们介绍了15种佛得角大洋碳酸盐岩(大西洋)中整个岩石和矿物分离相(磷灰石,黑云母和方解石)的新Sr-Nd同位素组成以及主要元素和痕量元素的浓度。钙和镁碳酸盐岩的痕量元素模式相对于佛得角玄武岩而言,存在着K,Hf,Zr和Ti的强烈消耗,以及Sr和REE的整体富集,认为碳酸盐岩和玄武岩之间存在不同的源组分。 Sr和Nd同位素比值显示出较小但显着的变化,定义了具有非放射源Sr和放射源Nd值的贫乏末端成员与与老海洋碳酸盐相容的“富集”末端成员之间的二元混合。通过与先前对佛得角玄武岩的研究相比较,我们将耗尽的最终成员解释为佛得角海洋岩石圈。因此,我们认为,海洋碳酸盐岩是由深部地幔羽与下部地幔中较低的〜4He /〜3He签名和碳酸化交代岩石圈的相互作用产生的,碳酸盐化交代岩石圈通过低度熔融产生了碳酸盐岩浆。碳酸盐岩的Sr-Nd组成和微量元素模式主张了一种由交代的,碳酸化的海洋地壳的部分熔融引起的交代作用剂。我们已经使用蒙特卡洛型模拟成功复制了该模型的主要地球化学特征。

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