Spatial distribution of organic pollutants in industrial construction and demolition waste and their mutual interaction on an abandoned pesticide manufacturing plant

摘要

A comprehensive field investigation of organic pollutants was examined in industrial construction and demolition waste (ICDW) inside an abandoned pesticide manufacturing plant. Concentrations of eight types of pesticides, a metabolite and two intermediates were studied. The ICDW was under severe and long-term contamination by organophosphorus, intermediates and pyrethroid pesticide with mean concentrations of 23 429, 3538 and 179.4 mg kg(-1), respectively. FT-IR analysis suggested that physical absorption and chemical bonding were their mutual interaction forms. Patterns of total pesticide spatial distribution showed good correlations with manufacturing processes spreading all over the plant both in enclosed workshops and in residues randomly dumped outside, while bricks and coatings were the most vulnerable to pollutants. Ultimately the fate of the OPPs was diversified as the immersion of ICDW in water largely transferred the pollutants into aquatic systems while exposure outside did not largely lead to pesticide degradation. The adoption of centralized collections for the disposal of wastes could only eliminate part of the contaminated ICDW, probably due to lack of knowledge and criteria. Correlation matrix and cluster analysis indicated that regulated disposal and management of polluted ICDW was effective, thus presenting the requirement for its appropriate disposal.