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Fly ash generated from heavy fuel incineration in power plants: Physical and chemical characteristics

机译:发电厂重油焚烧产生的粉煤灰:理化特性

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摘要

In Jordan, large amounts of fly ash (FA) are produced as a result of burning heavy fuel in power plants. The brackish granular flash ash was systematically analysed by different analytical techniques including scanning electron microscope (SEM), X-ray diffractometer (XRD), X-ray fluorescence (XRF). Fourier transform infrared spectroscopy (FTIR), lazier diffractometer (LD), Thermal gravimetric analysis (TGA) and acoustic and electroacous-tic spectrometer in order to investigate geometrical structure, morphology, surface chemistry and composition of the resulted FA. The FA was sampled form the places where heavy fuel is burned to produce electricity. This study revealed that about 50% of FA particles diameters were less than 530 nm. FA particles were predominantly appeared as smooth of mineral spheres. The FA was rich in C, S, Mg, V, Ni and Fe indicating the carbonaceous nature of this material. The Al and Si contents were insignificant. The size distribution, chemical and morphological properties of the FA particles were found to be log-normal. The FA contains high heavy metals content, particularly vanadium oxide (V2O5: 8.07 %wt) and nickel oxide (NiO: 0.91 %wt). Discussion on the physical and chemical characteristics of carbonaceous FA produced in power plants is addressed in this work.
机译:在约旦,由于发电厂燃烧重燃料而产生大量的飞灰(FA)。通过不同的分析技术,包括扫描电子显微镜(SEM),X射线衍射仪(XRD),X射线荧光(XRF),对微咸的颗粒状飞灰进行了系统分析。傅里叶变换红外光谱(FTIR),拉西尔衍射仪(LD),热重分析(TGA)以及声学和电声光谱仪,以研究所得FA的几何结构,形态,表面化学和组成。 FA是从燃烧重油发电的地方取样的。这项研究表明,约50%的FA颗粒直径小于530 nm。 FA颗粒主要表现为光滑的矿物球。 FA中富含C,S,Mg,V,Ni和Fe,表明该材料的碳质性质。 Al和Si含量微不足道。发现FA颗粒的尺寸分布,化学和形态学性质是对数正态的。 FA包含高重金属含量,尤其是氧化钒(V2O5:8.07 wt%)和氧化镍(NiO:0.91 wt%)。在这项工作中讨论了有关发电厂生产的碳质FA的物理和化学特性的讨论。

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