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Corrosion-erosion wear of refractory bricks in glass furnaces

机译:玻璃熔窑中耐火砖的腐蚀腐蚀磨损

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This paper presents the failure analysis of alumina-zirconia-silica (AZS) refractory bricks located in the glass level in the tank of a furnace for melting glass, since is the region where there is greater wear respect to the base. The wear of the refractory was evaluated after 4 years of campaigning, under thermal and mechanical loading during the glass manufacture. The analysis by scanning electron microscopy shows high porosity and the presence of alkalis is also detected from the glass composition, being the phase alumina-zirconia-silica (AZS).the one that shows better resistance to erosion wear by displacement of the molten glass. The analysis yielded the following mechanisms of chemical wear, removal of the vitreous phase toward the surface of the sample due to the increase in temperature of the furnace, and therefore attack by vapors through the porosity caused by the exudation of the vitreous phase, as well as deterioration of the microstructure of the refractory due to the formation of cracks. Because it is considered as the main problem in these types of furnaces, the erosion wear is related to the flows of convection currents within the tank, this occurs at the level of the glass, as it is at this point, where it has concentration of thermal and mechanical loads due to movement of the molten glass.
机译:本文介绍了位于玻璃熔窑炉内玻璃液位中的氧化铝-氧化锆-二氧化硅(AZS)耐火砖的失效分析,因为该区域相对于基座的磨损更大。经过四年的努力,在玻璃制造过程中的热负荷和机械负荷下评估了耐火材料的磨损。扫描电子显微镜的分析显示出高孔隙率,并且还从玻璃组合物中检测到了碱的存在,该相为氧化铝-氧化锆-二氧化硅(AZS)相。该相通过熔融玻璃的位移显示出更好的耐腐蚀磨损性。该分析产生以下化学磨损机理,由于炉温升高而将玻璃相移向样品表面,因此也受到由于玻璃相渗出而引起的气孔渗透蒸气的侵蚀由于裂纹的形成使耐火材料的微观结构恶化。由于它被认为是这类炉子中的主要问题,因此腐蚀磨损与罐内对流的流动有关,这种腐蚀发生在玻璃液面,因为此时的浓度很高。由于熔融玻璃的运动而产生的热负荷和机械负荷。

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