Sol-gel derived WO{sub}x and WO{sub}x/Pt films for direct methanol fuel cell catalyst applications

摘要

WO{sub}x was synthesised from W(OC{sub}2H{sub}5){sub}6 by two different methods using the sol-gel (SG) approach, Type 1 using ethanol as the solvent, while Type 2 was water-based. Films and powders made from these sols were subjected to analysis by cyclic voltammetry (CV), powder X-ray diffraction (XRD), and scanning electron microscopy (SEM). Sweep rate experiments revealed that compared to Type 1 films, Type 2 films have a significantly greater number of electroactive WO{sub}x sites, and that a smaller proportion of the total active sites are surface sites, indicative of a higher film porosity (consistent with the SEM results). XRD analysis showed that both Type 1 and Type 2 WO{sub}x were poorly crystallised. However, the patterns for the two WO{sub}x types were distinctly different, with Type 2 WO{sub}x giving a more well-defined pattern. WO{sub}x sols were also successfully combined with a pre-formed Pt sol. Unlike Pt-only catalysts, methanol oxidation currents on Type 2 WO{sub}x/Pt films did not decay rapidly with potential cycling, indicating the occurrence of co-catalytic behaviour, while Type 1 films were not very active, overall. The low resistance exhibited by the WO{sub}x component makes it suitable as an ionically and electronically conducting support for direct methanol fuel cell electrocatalysts.