Local electrochemical impedance measurements on inclusion-containing stainless steels using microcapillary-based techniques

摘要

MnS inclusions are good precursor sites for pitting corrosion of stainless steel. The objective of this paper was to quantify the passive properties of resulfurized stainless steel after immersion in chloride media. This was done by combining microcapillary techniques with electrochemical impedance spectroscopy and numerical analysis (specific equivalent circuit). It was shown that sulfur species produced in the electrolyte during the dissolution of inclusions react with the native passive film to CrS and FeSO_4. Local electrochemical impedance spectroscopy measurements provided data describing the behaviour of the affected matrix at the microscale. For example, the value of the charge transfer and migration of point defects resistance decreases from 51,700 Ω cm~2, in sites free of any metallurgical heterogeneity down to 12,200 Ω cm~2, in sites containing a high density of inclusions. It was also shown that the integrity of the microcapillary can be altered by the presence of high quantity of sulfur in the electrolyte. Local impedance data allowed the detection of such problems.