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Highly Mesoporous Carbon Electrodes for Electric Double-Layer Capacitors

机译:用于双层电容器的高介孔碳电极

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High Brunauer-Emmett-Teller method (BET) surface area and mesoporous activated carbons (ACs) were prepared by carbonization followed by activation of vinylidene chloride copolymer containing yttrium acetylacetonate Y( acac)_3. Their performance as electrodes for electric double-layer capacitors (EDLCs) in nonaqueous electrolyte solution was evaluated and compared with those of commercial microporous ACs. The specific EDLC capacitances of the ACs with high BET surface area are higher than those of the low BET surface area ACs at low discharge current. At high discharge current, the capacitances of the mesoporous ACs are higher than those of microporous ones. This is attributed to smooth movement of organic electrolyte ions in mesopores.
机译:通过碳化,然后活化包含乙酰丙酮钇Y(acac)_3的偏二氯乙烯共聚物,来制备高的Brunauer-Emmett-Teller方法(BET)的表面积和中孔活性炭(ACs)。对它们在非水电解液中作为双电层电容器(EDLC)的电极的性能进行了评估,并与商用微孔AC进行了比较。在低放电电流下,高BET表面积的AC的比EDLC电容高于低BET表面积AC的比EDLC电容。在高放电电流下,中孔AC的电容高于微孔AC的电容。这归因于有机电解质离子在中孔中的平滑运动。

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