Storage of sediment-associated heavy metals along the channelized Odra River, Poland

摘要

The importance of long-term storage of heavy metals in groyne fields, functioning over 150 years, is investigated for the River Odra (Oder), western Poland. Construction of groynes along the Odra preceded rapid development of heavy industrialization in the largest coal mine districts in Poland and the Czech Republic that resulted in persistent riverine pollution. The 187 km long Middle Odra reach was repeatedly channelized from the first half of the eighteenth century to the turn of the twentieth century, during which time partially filled groyne fields were dissected by new bank lines and groyne systems, with older groyne fields partially keyed into the floodplain. Consequently, concentrations of zinc, lead, cadmium, and copper within historically deposited groyne field sediments exceed local geochemical background levels by more than 60, 40, 15 and 10 times, respectively. Sediments contaminated with heavy metals occur within three distinctive geomorphic zones: zone I is up to 250 m wide and furthest from the present channel, comprising decimeter-thick polluted sediments, overlying eighteenth century sand and gravel bars; zone II represents the former nineteenth century groyne fields, with widths between 10 and 100 m, filled with as much as 3 m of polluted sediments; zone III represents the twentieth century groyne fields, which are several to a dozen metres wide and filled with polluted sediments averaging depths of more than 2 m. This investigation indicates that large and extensive sediment quantities of moderately polluted sediments are stored immediately along the banks of the River Odra. These sediments could be a significant secondary pollution source and therefore careful maintenance of contemporary bank protection structures is required.