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Timing of Gold and Arsenic Sulfide Mineral Deposition at the Getchell Carlin-Type Gold Deposit, North-Central Nevada

机译:内华达州中北部Getchell卡林型金矿床中金和硫化砷矿物的沉积时间

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Pregold mineralization at the Getchell Carlin-type gold deposit includes quartz and base metal vein mineralization associated with intrusion of a Cretaceous granodiorite stock. The veins contain minor pyrite and trace chalcopyrite, arsenopyrite, galena, and sphalerite. The pyrite is moderately coarse and, in thin section, has high relief, is well polished, and is fractured and locally cemented by the gold ore assemblage. White micas are associated with veins near the granodiorite intrusion. Gold was not observed or detected by fire assay analyses of samples or electron microprobe analyses of pyrites. Microprobe analyses show that pregold pyrites have near Stoichiometric compositions. Variable, low arsenic is present in pyrite in samples overprinted by gold mineralization. Secondary ion mass spectrometry (SIMS) analyses detected trace gold in the coarse, near-stoichiometric pyrite in overprinted samples. The pregold vein assemblage was fractured and cemented by gold ore-stage mineralization. The gold ore-stage assemblage consists of gold-and arsenic-enriched pyrite and marcasite encompassed by jasperoid and drusy quartz, and local late fluorite, orpiment, and galkhaite. The consistent spatial association of jasperoid and ore pyrite reflects their near-contemporaneous formation. The ore pyrite occurs as either fine, irregularly shaped grains, or rims on earlier, gold-free pyrite. In thin section, the pyrite is visibly distinct and has a low polishing relief and a poor polish. SIMS and electron microprobe analyses show that ore pyrites commonly contain 8 to 11 wt percent arsenic and as much as 2,400 ppm gold. Near the end of the ore stage, fluorite, orpiment, and galkhaite precipitated locally in open space created by faulting or limestone dissolution. Late ore-stage mineralization consists dominantly of open space-filling realgar and calcite, with minor quartz, stibnite, and framboidal pyrite. Realgar conforms to euhedral crystal faces of ore-stage quartz, fluorite, and galkhaite. Calcite filled most remaining open space and conforms to euhedral crystal faces of quartz, fluorite, and realgar.Significant textural observations argue against an earlier interpretation that the gold mineralization and arsenic minerals formed as two discrete events separated by 40 m.y. In a few areas where calcite and realgar are in contact with ore-stage quartz containing gold-bearing pyrite, realgar and calcite enclose gold-bearing pyrite grains. Massive realgar and calcite, and jasperoid requires close timing of these minerals and shows that there is no major time break separating ore-stage and late ore-stage mineral deposition. Textures indicate, instead, that the ore stage and late ore stage formed as part of a single, evolving hydrothermal system. The consistent successive overgrowth of younger minerals on perfectly preserved euhedral faces of older minerals supports the continuous evolution of the gold ore stage into the late ore stage. These results are consistent with fluid inclusions that indicate that paragenetically successive minerals precipitated from an aqueous ore fluid with consistent salinity and gas contents but at declining temperatures. Results show that, within error, the 34, 39, and 42 Ma ages determined for fluorite and galkhaite at Getchell and adularia at the nearly Twin Greeks mine, respectively, most closely approximate the timing of gold deposition at Getchell.
机译:Getchell Carlin型金矿床的预金矿化包括石英和贱金属脉状矿化,与白垩纪花岗闪长岩的侵入有关。脉中含有次要的黄铁矿和微量的黄铜矿,毒砂,方铅矿和闪锌矿。黄铁矿为中等粗度,并且在薄截面中具有高浮雕,被良好抛光,被金矿组合破碎和局部胶结。白色云母与花岗闪长岩侵入附近的脉相关。通过样品的火焰分析或黄铁矿的电子探针分析未观察到或检测到金。探针分析表明,预金黄铁矿具有接近化学计量的组成。黄铁矿中金矿化叠印的样品中存在可变的低砷。二次离子质谱(SIMS)分析叠印样品中粗近化学计量黄铁矿中检测到的痕量金。金矿阶段的矿化作用使前金矿脉组合破裂并固结。金矿阶段的组合包括富金和砷的黄铁矿和镁铁矿,被碧玉和富石英的石英所包围,以及局部的萤石,雌黄铁矿和方铅矿。碧玉和黄铁矿的一致空间联系反映了它们近乎同时期的形成。黄铁矿以细小,不规则形状的晶粒或边缘出现在较早的无金黄铁矿上。在薄截面中,黄铁矿明显不同,抛光浮雕低,抛光效果差。 SIMS和电子探针分析表明,黄铁矿通常含有8至11重量%的砷和多达2,400 ppm的金。在矿石阶段即将结束时,萤石,雌黄和方解石在由断层或石灰岩溶解产生的开放空间中局部沉淀。矿石后期矿化主要由充满空地的雄黄和方解石组成,还有少量的石英,辉石和黄铁矿黄铁矿。雄黄符合矿石级石英,萤石和方铅矿的正反面晶体面。方解石填满了剩余的大部分空旷空间,并与石英,萤石和雄黄的正反面晶体面相吻合。重要的纹理观察结果与早期的解释相反,即金矿化和砷矿物是由40 m.y隔开的两个离散事件形成的。在方解石和雄黄与含有含金黄铁矿的矿石级石英接触的一些地区,雄黄和方解石包裹了含金黄铁矿晶粒。大量的雄黄,方解石和碧玉需要这些矿物的时间紧迫,并且表明没有大的时间间隔可以分离矿石阶段和晚期矿石阶段的矿物。相反,纹理表明矿石阶段和晚期矿石阶段是作为单个不断发展的热液系统的一部分形成的。在完好保存的较老矿物的全面中,较年轻的矿物连续不断的过度生长,支持了金矿石阶段到晚期矿石阶段的不断演化。这些结果与流体包裹体相吻合,流体包裹体表明从岩矿中析出的矿渣和矿物质具有一致的盐度和气体含量,但温度却在下降。结果表明,在误差范围内,在几乎双胞胎希腊矿山的盖斯特(Getchell)和阿杜利亚(Adularia)确定的萤石和加尔卡岩的年龄分别为34、39和42 Ma,最接近盖斯特的金沉积时间。

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