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Consumption of Residual Char in Blast Furnace during Coal Injection-Slag/Carbon/Gas Interactions

机译:喷煤-炉渣/碳/气相互作用中高炉残渣的消耗

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摘要

One of the factors limiting the maximum rate ofcoal injection in the blast furnace is the accumulation of unburntchar .The interaction of unburnt char with slag ,hot metal and thegaseous phases could have a significant influence on charassimilation .This work examines the interaction of a low ironoxide bearing slag with different carbonaceous substrates withvarying levels of ash content (0.05%-12.25%) .Experiments wereconducted in a high temperature tube furnace at 1500°C (2732°F) in an argon atmosphere ,and the slag/carbon/gasinteractions were studied in-situ.The results showed that ash content and compositionof the carbonaceous substrates influenced theirwettability by the slag .With good wetting ,there isa significant decrease in the contact angle from theinitiation of melting .The carbonaceous materialsthat showed good wetting were reacting with the slagphase and resulting in a change in the slagcomposition .The consumption of carbon could occurwhen it is in contact with a slag bearing appreciablelevels of iron oxide ,for example .The kinetics of ironoxide reduction reaction could dictate theconsumption rate of carbon in a char present in theblast furnace during coal injection .The dissolutionof ash components in a char into the slag phase couldalso result in the consumption of char during coalinjection .These research topics are currently underinvestigation at the CRC for Black Coal Utilisationin the School of Materials Science andEngineering ,UNSW ,Sydney ;the investigationpresented here forms a part of the overall study.
机译:限制高炉喷煤最大速率的因素之一是未燃烧的焦炭的积累。未燃烧的焦炭与炉渣,铁水和气相的相互作用可能对焦化作用有重大影响。本文研究了低铁氧化物的相互作用。灰渣含量不同(0.05%-12.25%)的不同含碳基质的含渣炉渣。在氩气氛下于1500°C(2732°F)的高温管式炉中进行了试验,研究了炉渣/碳/气体的相互作用结果表明,炉渣影响了含碳基质的灰分含量和组成,润湿性良好,从熔化开始,接触角显着减小。润湿性良好的碳质材料与渣相和熔渣反应。导致炉渣成分发生变化。与炉渣bea接触时可能会消耗碳例如,环氧化铁的水平很高。氧化铁还原反应的动力学可能决定着喷煤过程中高炉中存在的焦炭中碳的消耗速率。煤灰中的灰分成分溶解到炉渣相中也可能导致焦炭的消耗这些研究主题目前正在悉尼新南威尔士大学材料科学与工程学院的CRC进行黑煤利用研究中;在此进行的研究构成了整体研究的一部分。

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