Preparation of Li_(1.5)Al_(0.5)Ti_(1.5)(PO4)3 solid electrolyte via a co-precipitation method

摘要

The co-precipitation method can make the materials react uniformly at molecular level and has the advantages of lower polycrystalline synthesized temperature and shorter sintering time. Therefore, it is expected that the mass production of Li_(1.5)Al_(0.5)Ti_(1.5)(PO4)3 (LATP) solid electrolyte would be possible by apphcation of the co-precipitation method for LATP preparation, hi this study, an application of the co-precipitation method for a preparation of LATP solid electrolyte is attempted. Crystallized LATP powder is obtained by heating precipitant containing Li, Al, Ti, and PO4 at 800 °C for 30 min. The LATP bulk sintered pellet is successfully prepared using the crystallized LATP powder by calcinating at 1,050 °C. The cross-sectional SEM images show that many crystal grains exist, and the grains are in good contact with each other, i.e., there is no void space. AH diffraction peaks of the pellet are attributed to LATP in XRD pattern. The sintered pellet is obtained by calcinating at 1,050 °C, which is more than 150 °C lower than that of conventional method. The LATP sohd electrolyte shows a good conductivity which is 1.4 x 10~(-3) S cm~(-1) for bulk and 1.5 x 10~(-4) S cm~(-1) for total conductivities, respectively.