Efficient synthesis and structural characterization of a post-metallocene alpha-olefin polymerization catalyst

Gauvin RM; Arbaoui A; Gautier E; Mortreux A; Berrier E; Nowogrocki G

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Efficient synthesis and structural characterization of a post-metallocene alpha-olefin polymerization catalyst

机译：后茂金属α-烯烃聚合催化剂的高效合成和结构表征

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摘要

We describe the fast one-pot synthesis of a chelating diamido dichloride titanium compound through sequential addition of the protonated ligand and triethylamine to TiCl4. The bisamido complex has been structurally characterized. A monoamido intermediate has been isolated.

机译：我们描述了通过依次添加质子化的配体和三乙胺到TiCl4中的螯合二酰氨基二氯化钛化合物的快速一锅合成。该比沙米多复合物已经在结构上表征。已分离出单酰胺中间体。

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《Inorganica Chimica Acta》 |2009年第1期|共4页
作者
Gauvin RM; Arbaoui A; Gautier E; Mortreux A; Berrier E; Nowogrocki G;
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正文语种 eng
中图分类无机化学;
关键词
Titanium; Amido ligand; Olefin polymerization; X-ray structure;

机译：钛;酰胺基配体;烯烃聚合;X射线结构;

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Efficient synthesis and structural characterization of a post-metallocene alpha-olefin polymerization catalyst

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