Synthesis, structure and thermochemical behavior of bis-(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)-(1,4,7,10,13,16-hexaoxa-cyclooctadecane)-strontium in comparison with its structural and thermochemical analogous

Tamara M. Polyanskaya; Mikhail A. Chistyakov; Elizaveta P. Simonenko; Vladimir G. Sevast’anov; Nikolay T. Kuznetsov

首页> 外文期刊>Inorganica Chimica Acta >Synthesis, structure and thermochemical behavior of bis-(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)-(1,4,7,10,13,16-hexaoxa-cyclooctadecane)-strontium in comparison with its structural and thermochemical analogous

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Synthesis, structure and thermochemical behavior of bis-(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)-(1,4,7,10,13,16-hexaoxa-cyclooctadecane)-strontium in comparison with its structural and thermochemical analogous

机译：双-（1,1,1,5,5,5-六氟-2,4-戊二酮基）-（1,4,7,10,13,16-六氧杂-环十八烷）-锶的合成，结构及热化学行为与结构和热化学类似物相比

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The trans-[M(18-crown-6)(C_5HO_2F_6)_2] (M = Ca, Sr, Ba, Pb) complexes have been synthesized and identified. The crystal structure of the Sr complex has been determined by X-ray diffraction. The basic structural unit is the mononuclear complex trans-[Sr(18-crown-6)(C_5HO_2F_6)_2]. The thermal properties of the complexes have been correlated to their structure. The melting and decomposition ranges of the Ca, Sr and Ba complexes and their sublimation temperatures at ～10~(-2) mm Hg have been determined. Experimental evidence is presented that the complexes are similar in volatility.

机译：合成并鉴定了反式[M（18-crown-6）（C_5HO_2F_6）_2]（M = Ca，Sr，Ba，Pb）配合物。 Sr配合物的晶体结构已经通过X射线衍射确定。基本结构单元是单核复合物反式[Sr（18-crown-6）（C_5HO_2F_6）_2]。配合物的热性质已经与其结构相关。确定了Ca，Sr和Ba配合物的熔化和分解范围，以及它们在〜10〜（-2）mm Hg下的升华温度。实验证明，该复合物的挥发性相似。

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《Inorganica Chimica Acta》 |2009年第15期|共6页
作者
Tamara M. Polyanskaya; Mikhail A. Chistyakov; Elizaveta P. Simonenko; Vladimir G. Sevast’anov; Nikolay T. Kuznetsov;
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原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Space shielding; Crown-ether; Bis-hexafluoroacetylacetonate; Volatility;

机译：空间屏蔽;冠醚;双六氟乙酰丙酮;挥发性;

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1. Synthesis, structure and thermochemical behavior of bis-(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)-(1,4,7,10,13,16-hexaoxa-cyclooctadecane)-strontium in comparison with its structural and thermochemical analogous [J] . Tamara M. Polyanskaya, Mikhail A. Chistyakov, Elizaveta P. Simonenko, Inorganica Chimica Acta . 2009,第15期

机译：双-（1,1,1,5,5,5-六氟-2,4-戊二酮基）-（1,4,7,10,13,16-六氧杂-环十八烷）-锶的合成，结构及热化学行为与结构和热化学类似物相比
2. Facile synthesis and characterization of new beta-diketonate silver complexes. single-crystal structures of (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(2,2 '-bipyridine)silver(I) and (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(N,N,N ',N '-tetramethyl [J] . Zanotto L, Benetollo F, Natali M, Chemical vapor deposition: CVD . 2004,第4期

机译：轻松合成和表征新的β-二酮银复合物。（1,1,1,5,5,5-hexafluoro-2,4-pentanedionato）（2,2'-bipyridine）silver（I）和（1,1,1,5,5， 5-六氟-2,4-戊二酮基）（N，N，N'，N'-四甲基
3. Facile Synthesis and Characterization of New β-Diketonate Silver Complexes. Single-Crystal Structures of (1,1,1,5,5,5- Hexafluoro-2,4-pentanedionato)(2,2′-bipyridine)silver(Ⅰ) and (1,1,1,5,5,5-Hexafluoro-2,4-pentanedionato)(N,N,N′,N′ -tetramethyleth [J] . Livio Zanotto, Franco Benetollo, Marco Natali, Advanced Materials . 2004,第17S期

机译：新型β-二酮银复合物的简便合成与表征。（1,1,1,5,5,5-六氟-2,4-戊二酮基）（2,2'-联吡啶）银（Ⅰ）和（1,1,1,5,5， 5-Hexafluoro-2,4-pentanedionato）（N，N，N'，N'-tetramethyletheth）

Synthesis, structure and thermochemical behavior of bis-(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)-(1,4,7,10,13,16-hexaoxa-cyclooctadecane)-strontium in comparison with its structural and thermochemical analogous

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