SUCCESSFUL ISOLATION AND X-RAY CRYSTAL STRUCTURE OF (TRIS(N-L-RHAMNOSYL-2-AMINOETHYL)AMINE)(SULFATE) NICKEL(II) HYDRATE TRIMETHANOL SOLVATE - [NI((L-RHA)(3)-TREN)(SO4)]CENTER-DOT-H2O-CENTER-DOT-3CH(3)OH

摘要

We have succeeded in the isolation and X-ray crystal structure determination of the octahedral nickel(II) complex [Ni((L-Rha)(3)-tren) (SO4)]. H2O . 3CH(3)OH (tren = tris(2-aminoethyl)amine; Rha = rhamnose) containing an N-glycoside derived from the reaction of L-Rha and tren. Crystal data: C27H62N4O20SNi, M(r) = 853.56, orthorhombic, space group P2(1)2(1)2(1), a = 16.035(4), b = 16.670(7), c = 15.38(1) Angstrom, Z = 4. [References: 18]