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Spin level inversion of magnetic dimer clusters at partial time inversion: The theoretical treatment and experimental confirmations

机译:部分时间反演时磁性二聚体团簇的自旋能级反演:理论处理和实验证实

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In this paper the transformation of the partial time inversion is discussed. For magnetic dimers it is shown that at partial time inversion the change of sign for the exchange integral takes place. This allows transforming the antiferromagnetic type of ordering into the ferromagnetic one and vice versa. Specifically, for magnetic dimers containing equivalent ions with S = 1/2, the partial time inversion transformation leads to spin level inversion. The possible 3d-3d and 4f-4f dimer clusters with antiferro- and ferromagnetic types of ordering are indicated. The electron paramagnetic resonance data for 3d-3d dimers proving the suggested statements are presented. [References: 10]
机译:本文讨论了部分时间反演的变换。对于磁性二聚体,表明在部分时间反转时交换积分的符号发生改变。这允许将反铁磁排序类型转换为铁磁排序,反之亦然。具体来说,对于包含等价离子且S = 1/2的磁性二聚体,部分时间反转转换会导致自旋能级反转。指出了可能的3d-3d和4f-4f二聚体簇,具有反铁磁性和铁磁性类型的排序。提供了证明建议的陈述的3d-3d二聚体的电子顺磁共振数据。 [参考:10]

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