Unusual supramolecular assembly and nonlinear optical properties of L-histidinium hydrogen malate

摘要

A new nonlinear optical material, L-histidinium hydrogen malate, has been synthesized. The crystal structure was determined at 90 K by single-crystal X-ray diffraction in order to analyze its supramolecular structure. A new building block type has been found. The malate anions form head-to-side infinite chains parallel to [100], via O-H center dot center dot center dot O interactions, instead of the usual head-to-tail infinite chains found in other hydrogen malate salts. The L-histidine cations form chains parallel to [100] via N-H center dot center dot center dot O hydrogen bonds, with cations of adjacent chains in anti-parallel way. The compound shows a good optical second-harmonic generation capability with an effective second-order susceptibility estimated to be 0.70 of that for potassium dihydrogen phosphate. (c) 2006 Elsevier Inc. All rights reserved.