首页> 外文期刊>Inorganic Chemistry Communications >Polynuclear heterometallic cadmium(II)/silver(I) phenylthiolates: Syntheses and structures of [Cd3(μ-SPh)6(μ3-SPh)4Ag4(PPh3)4] and [Cd3(OMe)2(μ-SPh)4 (μ3-SPh)8Ag8((μ-dppp)4] (dppp = 1,3-bis(disphenylphosphino)propane)
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Polynuclear heterometallic cadmium(II)/silver(I) phenylthiolates: Syntheses and structures of [Cd3(μ-SPh)6(μ3-SPh)4Ag4(PPh3)4] and [Cd3(OMe)2(μ-SPh)4 (μ3-SPh)8Ag8((μ-dppp)4] (dppp = 1,3-bis(disphenylphosphino)propane)

机译:多核异金属镉(II)/银(I)苯硫醇盐:[Cd3(μ-SPh)6(μ3-SPh)4Ag4(PPh3)4]和[Cd3(OMe)2(μ-SPh)4( μ3-SPh)8Ag8((μ-dppp)4](dppp = 1,3-双(二苯基膦基)丙烷)

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摘要

Reaction of [Me4N]2[Cd(SPh)4] and [Ag(PPh3)2NO3] (molar ratio = 1:1) in MeOH/CH2Cl2 (1:1) followed by recrystallization from DMF/Et2O yielded a neutral heptanuclear duster, [Cd3(μ-SPh)6(μ.3-SPh)4Ag4(PPh3)4] (1), while interaction of [Me4N]2[Cd(SPh)4] with AgNO3 and dppp (molar ratio = 4:6:3) gave a neutral unde-canuclear cluster [Cd3(OMe)2(μ.-SPh)4(μ3-SPh)8Ag8(μ.-dppp)4] (2). Crystal structures and photoluminescent properties of the two clusters in solid state were reported.
机译:[Me4N] 2 [Cd(SPh)4]和[Ag(PPh3)2NO3](摩尔比= 1:1)在MeOH / CH2Cl2(1:1)中反应,然后从DMF / Et2O中重结晶,得到中性七核除尘器,[Cd3(μ-SPh)6(μ.3-SPh)4Ag4(PPh3)4](1),而[Me4N] 2 [Cd(SPh)4]与AgNO3和dppp的相互作用(摩尔比= 4: 6:3)给出了中性的无核簇[Cd3(OMe)2(μ.-SPh)4(μ3-SPh)8Ag8(μ.-dppp)4](2)。报道了两个固态团簇的晶体结构和光致发光特性。

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