A new three-dimensional 4, 6-connected self-catenated net constructed from the [V8O_(23)]~(6-) polyoxoanions and metal-organic polymer

摘要

A new cobalt-vanadium composite solid, Co3(btx)5(H2O)V8o_(23) 1 (btx= 1,4-bis(triazol-1-ylmethyl)ben-zene) has been synthesized. Compound t exhibits a novel three-dimensional (3D) 4, 6-connected self-catenated net constructed from novel [V8O_(23)]6~ building blocks and the {C03(btx)5(H2O)2}~(6+) 3D metal-organic cation polymer. The magnetic study and electronic property of 1 have also been investigated.