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New ternary lanthanide coordination polymers of 1,4-naphthalenedicarboxylate with 1,10-phenanthroline

机译:1,4-萘二甲酸与1,10-菲咯啉的新型镧系配位聚合物

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摘要

Three isostructural 2-D square grid coordination polymers[LN_2(NDC)_3(phen)_2(H_2O)_2](Ln = La(1),Eu(2),Ho(3),NDC = 1,4-naphthalenedicarboxylate,phen = 1,10-phenanthroline)were synthesized by hydrothermal reactions of lanthanide chloride with 1,4-naphthalenedicarboxylic acid and phen.The 2-D coordination polymers were assembled into 3-D networks via O-H(centre dot)(centre dot)(centre dot)O hydrogen bond.The photophysical property,magnetic property and thermal stability of complex 2 were investigated.
机译:三种同构的二维方格配位聚合物[LN_2(NDC)_3(phen)_2(H_2O)_2](Ln = La(1),Eu(2),Ho(3),NDC = 1,4-萘二甲酸酯,通过镧系氯化物与1,4-萘二甲酸和phen的水热反应合成了phen = 1,10-菲咯啉.2-D配位聚合物通过OH(中心点)(centre dot)(研究了配合物2的光物理性质,磁性和热稳定性。

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