Pure white-light and color-tuning of PMMA-supported hybrid materials doped with (TTA)(3)-Zn2+-Eu3+ and (BA)(3)-Zn2+-Tb3+ complexes

摘要

Based on the doping of red-light-emitting 2 (IZn(L)(4-vinyl-Py)Eu(TTA)(3)]; H2L = N,N'-bis(salicylidene)cyclohexane-1,2-diamine, 4-vinyl-Py = 4-vinyl-pyridine, HTTA = 2-thenoyltrifluoroacetonate) and cyan-light-emitting 4 ( [Zn(L)(4-vinyl-Py)Tb(BA)(3)]; HBA = 1-phenyl-1,3-butanedione) in PMMA, hybrid materials of 2@4@PMMA with improved physical properties including color-tunable for white-light (CIE coordinate 0.373, 0319) were obtained. (C) 2016 Elsevier B.V. All rights reserved.