A novel triruthenium metal string complex with naphthylridylamide ligand: Synthesis, structure, magnetism, and molecular conductance

摘要

A triruthenium metal string, [Ru3(npa)4(NCS)2][PF6] (1), supported by naphthylridylamide (npa) ligands was successfully synthesized and is reported in this work. X-ray single crystal analysis shows that compound 1 exhibits a nonlinear [Ru3]~(7+) backbone (z = 170.26(3)°) with long Ru-Ru bond lengths (2.3554(8) A). The long Ru-Ru distances observed for 1 decrease the Ru-Ru interactions and electric conductance. Magnetic measurements indicate that compound 1 is in a S = 1/2 state. DFT calculations suggest that this unpaired electron occupies the π~* orbital which is stabilized by π-acid NCS~- ligands and thus weakening the Ru-Ru rt interaction.