Aldol reaction of tert-butyldimethylsilyloxy allene with aromatic aldehydes, a direct route to acrolein aldol products

Amarjit Kaur; Gurmeet Kaur; Sanjay Trehan

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Aldol reaction of tert-butyldimethylsilyloxy allene with aromatic aldehydes, a direct route to acrolein aldol products

机译：叔丁基二甲基甲硅烷氧基丙二烯与芳族醛的醛醇缩合反应，直接制得丙烯醛醛醇缩醛产物

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摘要

tert-Butyldimethylsilyloxyallene reacts with aromatic aldehydes in the presence of BF_3.Et_2O to give corresponding aldol products.

机译：在BF_3.Et_2O的存在下，叔丁基二甲基甲硅烷基氧丙烯与芳族醛反应，得到相应的醛醇产物。

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《Indian Journal of Chemistry, Section B. Organic Including Medicinal》 |1998年第10期|共3页
作者
Amarjit Kaur; Gurmeet Kaur; Sanjay Trehan;
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正文语种 eng
中图分类化学;化学工业;
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1. Aldol reaction of tert-butyldimethylsilyloxy allene with aromatic aldehydes, a direct route to acrolein aldol products [J] . Amarjit Kaur, Gurmeet Kaur, Sanjay Trehan Indian Journal of Chemistry, Section B. Organic Including Medicinal . 1998,第10期

机译：叔丁基二甲基甲硅烷氧基丙二烯与芳族醛的醛醇缩合反应，直接制得丙烯醛醛醇缩醛产物
2. Zinc(II)-Catalyzed Intermolecular Hydrative Aldol Reactions of 2-En-1-ynamides with Aldehydes and Water to form Branched Aldol Products Regio- and Stereoselectively [J] . Jadhav Appaso Mahadev, Pagar Vinayak Vishnu, Huple Deepak B., Angewandte Chemie . 2015,第12期

机译：锌（II）催化的2-En-1-酰胺与醛和水的分子间氢化羟醛反应形成区域和立体选择性的支链羟醛产物
3. Tuning the sense of product stereochemistry in aldol reactions of acetone and aromatic aldehydes in the presence of water with a single chiral catalyst [J] . Gurka Andras A., Szori Kornel, Szollosi Gyoergy, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2015,第52期

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4. Germanium(II)-Mediated Reductive Cross-Aldol Reaction of Aldehydes:Synthesis of Aldols with Diastereocontrolled Quaternary Carbon Centers [C] . Shin-va Tanaka, Makoto Yasucla, Akio Baba Symposium on Organometallic Chemistry . 2007

机译：锗（II）膜的蛋白质介导的醛 - 醛醛 - 醛醇的合成与非杀螨科季碳中心合成
5. Strained silacycles in organic synthesis: The tandem aldol-allylatio/aldol-aldol reaction and their asymmetric variations. [D] . Wang, Xiaolun. 2005

机译：有机合成中的应变硅杂环化合物：串联的羟醛-烯丙基比/羟醛-羟醛反应及其不对称变化。
6. Asymmetric Catalysis Special Feature Part I: Chiral phosphoramide-catalyzed enantioselective directed cross-aldol reactions of aldehydes [O] . Scott E. Denmark, Tommy Bui 2004

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7. Base-Mediated Cascade Aldol Addition and Fragmentation Reactions of Dihydroxyfumaric Acid and Aromatic Aldehydes: Controlling Chemodivergence via Choice of Base, Solvent, and Substituents [O] . George Ward, Charles L. Liotta, Ramanarayanan Krishnamurthy, 2018

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Aldol reaction of tert-butyldimethylsilyloxy allene with aromatic aldehydes, a direct route to acrolein aldol products

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