Thermal stability of water and hydroxyl on the surface of the Moon from temperature-programmed desorption measurements of lunar analog materials

摘要

The adsorption of molecular water onto lunar analog materials was investigated under ultra-high vacuum with the goal to better understand the thermal stability and evolution of water on the lunar surface. Temperature-programmed desorption (TPD) experiments show that lunar-analog basaltic-composition glass is hydrophobic, with water-water interactions dominating over surface chemisorption. This suggests that lunar agglutinates will tend not to adsorb water at temperatures above where water clusters and multilayer ice forms. The basalt JSC-1A lunar mare analog, which is a complex mixture of minerals and glass, adsorbs water above 180. K with an adsorption profile that extends to 400. K, showing evidence for a continuum of water adsorption sites. Bancroft albite adsorbs more water, more strongly, than JSC-1A, with a well-defined desorption peak near 225. K. This suggests that mineral surfaces will adsorb more water than mare or mature (glassy, agglutinate rich) surfaces and may explain the association of water with fresh feldspathic craters at high latitudes. The activation energies for the thermal desorption of water from these materials were determined, and along with values from the literature, used to model the grain-to-grain migration of water within the lunar regolith. These models suggest that a combination of recombinative desorption of hydroxyl along with molecular desorption of water and its subsequent migration within and out of the regolith may explain observed diurnal variations in the distribution of water and hydroxyl on the illuminated Moon.