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Hydrodynamic Equations and Correlation Functions

机译:流体力学方程和相关函数

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The response of a system to an external disturbance can always be expressed in terms of time dependent correlation functions of the undisturbed system. More particularly the linear response of a system disturbed slightly from equilibrium is characterized by the expectation value in the equilibrium ensemble, of a product of two space- and time-dependent operators. When a disturbance leads to a very slow variation in space and time of all physical quantities, the response may alternatively be described by the linearized hydrodynamic equations. The purpose of this paper is to exhibit the complicated structure the correlation functions must have in order that these descriptions coincide. From the hydrodynamic equations the slowly varying part of the expectation values of correlations of densities of conserved quantities is inferred. Two illustrative examples are considered: spin diffusion and transport is an ordinary one-component fluid. Since the descriptions are equivalent, all transport processes which occur in the nonequilibrium system must be exhibited in the equilibrium correlation functions. Thus. when the hydrodynamic equations predict the existence of a diffusion process, the correlation functions will include a part which satisfies a diffusion equation. Similarly when sound waves occur in the nonequilibrium system, they will also be contained in the correlation functions. The description in terms of correlation functions leads naturally to expressions for the transport coefficients like those discussed by Kubo. The analysis also leads to a number of sum rules relating the dissipative linear coefficients to thermodynamic derivatives. It elucidates the peculiarly singular limiting behavior these correlations must have.
机译:系统对外部干扰的响应始终可以用不受干扰的系统的时间相关函数来表示。更具体地,受平衡轻微干扰的系统的线性响应的特征在于,平衡系综中的期望值是两个依赖于空间和时间的算子的乘积。当扰动导致所有物理量的空间和时间变化非常缓慢时,可以通过线性流体动力学方程描述响应。本文的目的是展示相关函数必须具有的复杂结构,以使这些描述一致。从流体力学方程式中,可以推断出守恒量密度相关性的期望值的缓慢变化部分。考虑两个示例性例子:自旋扩散和传输是普通的单组分流体。由于描述是等价的,因此必须在平衡相关函数中显示在非平衡系统中发生的所有传输过程。从而。当流体力学方程式预测存在扩散过程时,相关函数将包括满足扩散方程式的部分。类似地,当声波在非平衡系统中发生时,它们也将包含在相关函数中。关于相关函数的描述自然会导致像Kubo讨论的那样的传输系数表达式。分析还得出许多求和规则,这些规则将耗散线性系数与热力学导数相关。它阐明了这些关联必须具有的奇异的极限行为。

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