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CO2 Adsorption over Zinc Oxide Impregnated NaZSM-5 Synthesized Using Rice Husk Ash

机译:稻壳灰合成氧化锌浸渍的NaZSM-5上的CO2吸附

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摘要

Zinc oxide (5, 10 and 15 wt %) impregnated NaZSM-5 zeolite synthesized using rice husk ash as silica source was tested for CO2 adsorption. The materials were characterized by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, CO2-temperature programmed desorption and Brunauer-Enimett-Teller techniques. The heat of the reaction (AH,) derived from differential scanning calorimetry analysis for NaZSM-5 (10 %) to be 495 Btu/Lb. The maximum CO2 adsorption capacity of NaZSM-5 (10 %) is 140 mg/g of sorbent. Extraction of silica from the agricultural waste, rice husk and its use in the zeolite synthesis is an added advantage in this study. Hence, from the study it is concluded that zinc oxide impregnated NaZSM-5 could be treated as novel material for CO2 adsorption as they were found to be regenerable, selective and recyclable.
机译:测试了用稻壳灰作为二氧化硅源合成的浸渍了氧化锌(5、10和15 wt%)的NaZSM-5沸石的CO2吸附性能。通过X射线衍射,扫描电子显微镜,能量色散X射线分析,CO2程序升温脱附和Brunauer-Enimett-Teller技术对材料进行了表征。由差示扫描量热法分析得出的NaZSM-5(10%)的反应热(AH,)为495 Btu / Lb。 NaZSM-5(10%)的最大CO2吸附容量为140 mg / g吸附剂。从农业废料,稻壳中提取二氧化硅并将其用于沸石合成是这项研究的另一个优势。因此,从该研究得出的结论是,由于氧化锌浸渍的NaZSM-5具有可再生,选择性和可回收性,因此可被视为新型的CO2吸附材料。

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