SELECTIVE CATALYTIC REDUCTION (SCR) OF NO BY AMMONIA OVER V2O5/TiO2 CATALYST IN A CATALYTIC FILTER MEDIUM AND HONEYCOMB REACTOR: A KINETIC MODELING STUDY

摘要

The present study addresses a numerical modeling and simulation based on the available knowledge of SCR kinetics for prediction of NO conversion over a V2O5/TiO2 catalyst through a catalytic filter medium and honeycomb reactor. After introducing the NH3-SCR system with specific operational criteria, a reactor model was developed to evaluate the effect of various operating parameters such as flue gas temperature, velocity, NH3/NO molar ratio, etc., on the SCR process. Computational investigations were performed based on the proposed model and optimum operational conditions were identified. Simulation results indicate that SCR performance is substantially under the effects of reactant concentration and operating temperature, so that the concentration of unreacted ammonia emitted from reactor discharge (ammonia slip) increases significantly at NH3/NO ratios of more than 1.14 and operating temperatures less than 360 degrees C and 300 degrees C, respectively, in the catalytic filter medium and honeycomb reactor. The results also show that there are three sections in NO conversion variation versus changing temperature and the required conversion with a maximum of almost 87% and low level of ammonia slip can be achieved at the NH3/NO ratio of 1 and temperature range of 240-360 degrees C in both reactors.