Palladacycle-Catalyzed Tandem Allylic Amination/Allylation Protocol for One-Pot Synthesis of 2-Allylanilines from Allylic Alcohols

摘要

An efficient methodology involving the predominant formation of C-C bonds is described for the first direct synthesis of 2-allylanilines from allylic alcohols via a one-pot tandem allylic amina-tion/allylation protocol catalyzed by a palladacycle under mild conditions without the requirement for additional activators.