Free-standing flexible film as a binder-free electrode for an efficient hybrid deionization system

摘要

In recent years, capacitive deionization (CDI) has emerged as an energy efficient and cost-effective technology for the desalination of brackish water. However, high energy consumption and poor desalting efficiency at high salinity levels have hampered the application of CDI for seawater (approximate to 35000 mg L-1). A novel method of CDI termed hybrid capacitive deionization (HCDI) employs the use of a faradaic electrode paired with a capacitive electrode. Doing so increases the salt removal capacity to approximately three times that of conventional activated carbon (AC) materials (approximate to 10 mg g(-1)). Herein, we report experimental results of our HCDI cell using free-standing Na2Ti3O7-CNT@reduced graphene oxide (NCNT@rGO) film as a binder-free negative and activated carbon@reduced graphene oxide (AC@rGO) film as the positive electrode. The HCDI cell is operated under a constant current mode. During desalination, sodium ions are intercalated into the negative electrode (NCNT@rGO) whereas chloride ions are adsorbed onto the surface of the positive electrode (AC@rGO). We observed a high removal capacity of 129 mg g(-1) at the low energy consumption of 0.4 W h g(-1) for a salt concentration of approximate to 3000 mg L-1 at 50 ml min(-1) flow rate. The higher performance of our electrodes over conventional ones (approximate to 109 mg g(-1), 0.68 W h g(-1)) is attributed to the absence of binders or conductive additives and the unique nano-architectured sandwich structure of NCNT@rGO. The advantageous features of our electrodes shed new insight into the development of CDI materials and show promise for low-cost, scalable systems.