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首页> 外文期刊>Applied radiation and isotopes: including data, instrumentation and methods for use in agriculture, industry and medicine >The resolution-enhanced ESR powder spectrum of γ-ray and UV-light irradiated unbound- and silicone-bound-alanine and its satellite lines
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The resolution-enhanced ESR powder spectrum of γ-ray and UV-light irradiated unbound- and silicone-bound-alanine and its satellite lines

机译:γ-射线和紫外光辐照的未结合和有机硅结合的丙氨酸及其卫星谱的分辨率增强的ESR粉末光谱

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摘要

From power saturated and resolution-enhanced ESR powder patterns of irradiated alanine it was possible to discern between the octet of satellite and allowed lines of these patterns. Additionally, differences between ESR spectra of γ-ray irradiated silicone-bound- and unbound-alanine free radicals are also observed when the induced free radicals are subjected to UV-light. These spectral differences and those from power saturated spectra are correlated in such a way that the existence of secondary free radicals and crystal defects may be needed to explain present results.
机译:从辐照的丙氨酸的功率饱和和分辨率增强的ESR粉末图案中,可以辨别卫星的八位位组和这些图案的允许线。另外,当诱导的自由基经受紫外线照射时,还观察到γ射线辐照的硅氧烷键合的和未键合的丙氨酸自由基的ESR谱之间的差异。这些光谱差异与功率饱和光谱的光谱差异相关,因此可能需要存在次级自由基和晶体缺陷来解释目前的结果。

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