Secondary ion mass spectrometry signatures for verifying declarations of fissile-material production

摘要

Direct analysis of uranium enrichment facility components were performed using secondary ion mass spectrometry (SIMS). A standard protocol was developed to enable preparation of SIMS samples from a corroded pipe piece without disturbing the corrosion layer. Unique uranium, oxygen and fluorine containing signatures were discovered in the corrosion layer by performing a mass scan of the region of interest from 230 to 280 amu. These signatures identified the source of the corrosion layer as uranium hexafluoride (UF6) or an associated hydrolysis product. Isotopic analysis of the corrosion layer determined enrichment of U-235 to a value of 0.0116 +/- 0.0019 for the U-235/U-238 isotopic ratio as compared to the NIST traceable standard (CRM 112-A) with a natural U-235/U-238 isotopic ratio of 0.007254 +/- 0.000004. SIMS depth analysis revealed that the corrosion layer was isotopically homogenous to a depth of similar to 23.5 mu m. Optical profilometry measurements prior to and following SIMS depth analysis were used to determine a sputter rate of 0.48 nm/s for 18.5 keV O- ion bombardment of the corrosion layer. The data presented is conclusive evidence that SIMS depth analysis can be used to identify novel nuclear archeology signatures from uranium enrichment components and perform meaningful isotopic analysis of these signatures. (C) 2014 Elsevier Ltd. All rights reserved.