Influence of pH and temperature on the early stage of mica alteration

摘要

Mineral dissolution and precipitation reactions actively participate in controlling fluid chemistry during water-rock interaction. In this study, the changes in the biotite and muscovite basal surface nano-morphology were evaluated during interaction with fluids of different pH (pH = 1.1, 3.3 and 5.7) at different temperatures (T=25°, 120°, and 200. °C). Results show that at the nanometre scale resolution of the atomic force microscope (AFM), dissolution generates etch pits with a stair-shaped pattern over the (0. 0. 1) surface. The flux of dissolved elements decreases when pH increases. However, at pH _5.7, a change was found in the flux after 42. h of reaction when abundant gibbsite and kaolinite coat the dissolving mineral surface. This phenomenon was widely observed at edges of the etch pits by AFM. It was also found that an increase in temperature produces an enhancement in the elemental flux in both micas. Dissolution regime changes after less than one day of interaction at high temperature because of abundant coating formation over the etch pits and edges. The results demonstrate the key role of nanometre size neogenic phases in the control of elemental flux from mica surfaces to solution. The formation of nanometre size coatings, blocking the sites active for dissolution, appears to control the alteration of phyllosilicates even at the early stage of the interaction.