Hydrothermal doping method for preparation of Cr~(3+)-TiO_2 photocatalysts with concentration gradient distribution of Cr~(3+)

摘要

Cr~(3+)-doped anatase titanium dioxide photocatalysts were prepared by the combination of sol-gel process with hydrothermal treatment.The samples were characterized by UV-vis diffuse reflectance spectroscopy,X-ray diffraction (XRD),Brunauer-Emmett-Teller (BET) specific surface area (SBETX transmission electron microscopy (TEM),atomic absorption flame emission spectroscopy (AAS),electron paramagnetic resonance (EPR) spectroscopy and X-ray photoelectron spectroscopy (XPS).It was confirmed that Cr substitutes Ti~(4+) in TiO_2 lattice in trivalent ionic state,and the concentrations of dopants Cr~(3+) decrease from the exterior to the interior of doped TiO_2.The photocatalytic activity of Cr-TiO_2 was investigated for the photocatalytic degradation of XRG aqueous solution both under UV and visible light irradiation.Due to the excitation of 3d electron of Cr~(3+) to the conduction band of TiO_2,Cr-TiO_2 shows a good ability for absorbing the visible light to degrade XRG.Doping of chromium ions effectively improves the photocatalytic activity under both UV light irradiation and visible light irradiation with an optimal doping concentration of 0.15% and 0.2%,respectively.The special distribution of dopants Cr~(3+) seems having a good effect on enhancing the photocatalytic activity of Cr-TiO_2.