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首页> 外文期刊>Electroanalysis >Electrochemical Determination of Neurotransmitters at Crown Ether Modified Carbon Nanotube Composite: Application for Sub‐nano‐sensing of Serotonin in Human Serum
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Electrochemical Determination of Neurotransmitters at Crown Ether Modified Carbon Nanotube Composite: Application for Sub‐nano‐sensing of Serotonin in Human Serum

机译:冠醚改性碳纳米管复合材料中神经递质的电化学测定:人血清中血清中血清素的亚纳米感测

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摘要

Abstract > We propose an electrochemical sensor based on applying two successive thin layers from a mixture of multiwalled carbon nanotubes‐ionic liquid crystal and crown ether at glassy carbon electrode surface (GC/(CNTs‐ILC)/Crown). The sensor was used for sensitive determination of neurotransmitters based on effective synergism between its components. The compact conducting surface of (CNTs ‐ ILC) with large surface area allowed the assembling of stable host‐guest inclusion complexes between crown ethers and neurotransmitters. The GC/(CNTs‐ILC)/Crown exhibited excellent electro‐catalytic activity toward the determination of serotonin (ST) in a wide linear dynamic range: 0.005?μmol?L ?1 to 100?μmol?L ?1 . In the concentration range 0.005?μmol?L ?1 to 1?μmol?L ?1 , the detection limit is 2.03×10 ?10 ?mol?L ?1 and quantification limit is 6.78×10 ?10 ?mol?L ?1 with correlation coefficient 0.999. The sensor was successfully applied for ST detection in human serum samples with satisfied recovery results. The sensor showed excellent analytical performance for the determination of ST in terms of low detection limit, good sensitivity and reproducibility. Furthermore excellent anti‐interference ability and simultaneous determination of ST in presence of other compounds as ascorbic acid, dopamine and antidepressant drug were achieved. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span>None </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-22546/'>《Electroanalysis》</a> <b style="margin: 0 2px;">|</b><span>2019年第7期</span><b style="margin: 0 2px;">|</b><span>共11页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Atta Nada F.&option=202" target="_blank" rel="nofollow">Atta Nada F.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ahmed Yousef M.&option=202" target="_blank" rel="nofollow">Ahmed Yousef M.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Galal Ahmed&option=202" target="_blank" rel="nofollow">Galal Ahmed;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Chemistry Department Faculty of ScienceCairo University12613 Giza Egypt;</p> <p>Chemistry Department Faculty of ScienceCairo University12613 Giza Egypt;</p> <p>Chemistry Department Faculty of ScienceCairo University12613 Giza Egypt;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4817.html" title="电化学、电解、磁化学">电化学、电解、磁化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Multiwalled carbon nanotubes&option=203" rel="nofollow">Multiwalled carbon nanotubes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ionic liquid crystal&option=203" rel="nofollow">Ionic liquid crystal;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Crown ether&option=203" rel="nofollow">Crown ether;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Serotonin&option=203" rel="nofollow">Serotonin;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Neurotransmitters&option=203" rel="nofollow">Neurotransmitters;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Human serum&option=203" rel="nofollow">Human serum;</a> </p> <div class="translation"> 机译:多壁碳纳米管;离子液晶;冠状醚;血清素;神经递质;人血清; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" 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Min Wu</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wanrong Tang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Wanrong Tang</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Junlin Gu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Junlin Gu</a> <span> <a href="/journal-cn-56200/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 美国分析化学(英文) </a> </span> <span> . 2013</span><span>,第6期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-64500_thesis/020222830611.html">以铂双金属奈米催化剂修饰奈米碳管电极的电化学行为(Electrochemical Activity of Carbon Nanotube Electrodes Modified by Pt-Based Bimetallic Nanocatalysts)</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chien-Te Hsieh&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . Chien-Te Hsieh</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=谢建德&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,谢建德</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chia-Yi Lin&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Chia-Yi Lin</a> <span> <a href="/conference-cn-64500/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第五届全国化学工程与生物化工年会 </a> <span> <span> . 2008</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06130406100460.html">Carbon nanotube field-effect transistor modified with bromocresol green and determination of human serum albumin using the same</a> <b>[P]</b> . <span> 外国专利: <!-- 韩国专利: --> KR20170135370A </span> <span> . 2017-12-08</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:溴甲酚绿修饰的碳纳米管场效应晶体管及其测定人血清白蛋白的方法 </span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06130415019802.html">process for the production of polymeric composites containing modified carbon nanotubes, composite polimerowy containing modified carbon nanotubes and its application</a> <b>[P]</b> . <span> 外国专利: <!-- --> PL404703A1 </span> <span> . 2015-01-19</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:含改性碳纳米管的聚合物复合材料的生产方法,含改性碳纳米管的复合聚合物及其应用 </span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130424494266.html">Dispersion agent for carbon nanotube, carbon nano composite, carbon nanotube film and method for manufacturing the carbon nano tube film</a> <b>[P]</b> . <span> 外国专利: <!-- 韩国专利: --> KR101007064B1 </span> <span> . 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