The perchlorate effect with metallo-cyanide complexes on cellulose anion exchange thin layers

摘要

The effect of NaClO4 concentration on the R-f value for [Fe(CN)(6)](4-); [Fe(CN)(6)](3-), [FeNO(CN)(5)](2-), [Au(CN)(2)](-), CrO42-, [PtCl4](2-), CNS- and [AuCl4](-) on DEAE cellulose thin layers is studied. Perchlorate is shown to have strong desorbing effect on all the anions, known as the perchlorate effect. Nitrate behaves similarly but less effectively. (C) 1998 Elsevier Science B.V. [References: 5]