Radiochemical Neutron Activation Analysis for Trace Chlorine in Steels and Alloys

摘要

Chlorine is usually present at low concentrations m reactor materials and thermal neutron activation of ↑(35)C1 produces ↑(36)CI, which has a long half-life and is a radio-nuclide of significance in nuclear waste disposal. This paper describes a radiochemical method that has been developed to measure low concentrations of Cl in reactor stainless steels, so that the amount of 36CI in radioactive wastes can be estimated. The method is based on the irradiation of a 1 g sample in a thermal neutron flux of 10↑(16), n m↑(-2) s↑(-1), followed by dissolution in HNO↑(3) with the addition of stable KCI carrier/tracer. The Cl is precipitated as AgCl, and the recovery is measured gravimetrically. The ↑(38)C1, which has a half-life of 37 rain, is measured with γ-ray spectrometry. The entire process, from irradiation to the end of counting, takes ~1.5 h. The recovery is near. quantitative, and the detection limit for Cl in most stainless steels is below 1 mg/kg.