Alternative coulometric signal readout based on a solid-contact ion-selective electrode for detection of nitrate

摘要

Traditional potentiometric NO3--selective electrodes suffer from a fundamental limitation of the Nernst slope (59.1 mV/dec at 25 degrees C) due to the relationship between the potential and the logarithmic of ionic activity. Herein, a coulometric signal readout is proposed instead of the potentiometric response for detection of NCii based on an ordered mesoporous carbon (OMC)-based solid-contact ion-selective electrode (ISE). The mechanism for obtaining the coulometric signal is based on the electrical double layer capacitance of OMC compensating the potential change at the ion-selective membrane/solution interface during the measurements under the control of a constant applied potential. Under the optimized conditions, the coulometric signal for the OMC-based solid-contact NO3--ISE shows two linear responses in the activity range of 1.0 x 10(-6)-8.0 x 10(-6) M and 8.0 x 10(-6)-8.0 x 10(-4) M, and the detection limit is 4.0 x 10(-7) M (3 sigma/s). The proposed coulometric response also shows excellent reproducibility and stability in the presence of O-2 and CO2 and light on/off. Additionally, the coulometric response shows acceptable and reliable results for detection of NO3- in mineral water as compared to the traditional potentiometric response and the ion chromatography. This work provides a promising alternative signal readout for detection of ions by using solid-contact ion-selective electrodes. (C) 2020 Elsevier B.V. All rights reserved.