Room-Temperature Ferroelectric Material Composed of a Two-Dimensional Metal Halide Double Perovskite for X-ray Detection

摘要

Although two-dimensional (2D) metal-halide double perovskites display versatile physical properties due to their huge structural compatibility, room-temperature ferroelectric behavior has not yet been reported for this fascinating family. Here, we designed a room-temperature ferroelectric material composed of 2D halide double perovskites, (chloropropylammonium)(4)AgBiBr8, using an organic asymmetric dipolar ligand. It exhibits concrete ferroelectricity, including a Curie temperature of 305 K and a notable spontaneous polarization of approximate to 3.2 mu C cm(-2), triggered by dynamic ordering of the organic cation and the tilting motion of heterometallic AgBr6/BiBr6 octahedra. Besides, the alternating array of inorganic perovskite sheets and organic cations endows large mobility-lifetime product (mu tau=1.0x10(-3) cm(2) V-1) for detecting X-ray photons, which is almost tenfold higher than that of CH3NH3PbI3 wafers. As far as we know, this is the first study on an X-ray-sensitive ferroelectric material composed of 2D halide double perovskites. Our findings afford a promising platform for exploring new ferroelectric materials toward further device applications.