Clarification of Decomposition Pathways in a State‐of‐the‐Art Lithium Ion Battery Electrolyte through 13C‐Labeling of Electrolyte Components

Henschel Jonas; Peschel Christoph; Klein Sven; Horsthemke Fabian; Winter Martin; Nowak Sascha

摘要

Abstract > The decomposition of state‐of‐the‐art lithium ion battery (LIB) electrolytes leads to a highly complex mixture during battery cell operation. Furthermore, thermal strain by e.g., fast charging can initiate the degradation and generate various compounds. The correlation of electrolyte decomposition products and LIB performance fading over life‐time is mainly unknown. The thermal and electrochemical degradation in electrolytes comprising 1? <sc>m</sc> LiPF <sub>6</sub> dissolved in 13 C <sub>3</sub> ‐labeled ethylene carbonate (EC) and unlabeled diethyl carbonate is investigated and the corresponding reaction pathways are postulated. Furthermore, a fragmentation mechanism assumption for oligomeric compounds is depicted. Soluble decomposition products classes are examined and evaluated with liquid chromatography‐high resolution mass spectrometry. This study proposes a formation scheme for oligo phosphates as well as contradictory findings regarding phosphate‐carbonates, disproving monoglycolate methyl/ethyl carbonate as the central reactive species. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 在电池单元操作期间，最先进的锂离子电池（Lib）电解质的分解导致高度复杂的混合物。此外，通过例如热应变。，快速充电可以引发劣化并产生各种化合物。电解质分解产物和Lib性能逐渐消耗的情况主要是未知的。包含1的电解质中的热和电化学降解？ <sc> m </ sc> Lipf. <sub> 6 </ sub> 溶解在 13 </ sup> C <sub> 3 </ sub> - 研究 - 标记的碳酸亚乙酯（EC）和未标记的碳酸二乙酯，并假设相应的反应途径。此外，描绘了寡聚化合物的碎片机理假设。用液相色谱 - 高分辨率质谱法检测和评估可溶性分解产物。该研究提出了寡核苷酸磷酸盐的形成方案以及关于磷酸盐 - 碳酸盐的矛盾结果，使单糖醇甲基/碳酸乙酯作为中枢反应性物种。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第15期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Henschel Jonas&option=202" target="_blank" rel="nofollow">Henschel Jonas;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Peschel Christoph&option=202" target="_blank" rel="nofollow">Peschel Christoph;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Klein Sven&option=202" target="_blank" rel="nofollow">Klein Sven;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Horsthemke Fabian&option=202" target="_blank" rel="nofollow">Horsthemke Fabian;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Winter Martin&option=202" target="_blank" rel="nofollow">Winter Martin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nowak Sascha&option=202" target="_blank" rel="nofollow">Nowak Sascha;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>MEET Battery Research CenterUniversity of MünsterCorrensstra?e 46 48149 Münster Germany;</p> <p>MEET Battery Research CenterUniversity of MünsterCorrensstra?e 46 48149 Münster Germany;</p> <p>MEET Battery Research CenterUniversity of MünsterCorrensstra?e 46 48149 Münster Germany;</p> <p>MEET Battery Research CenterUniversity of MünsterCorrensstra?e 46 48149 Münster Germany;</p> <p>MEET Battery Research CenterUniversity of MünsterCorrensstra?e 46 48149 Münster Germany;</p> <p>MEET Battery Research CenterUniversity of MünsterCorrensstra?e 46 48149 Münster Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=13C-labeling&option=203" rel="nofollow">13C-labeling;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrolyte decomposition pathways&option=203" rel="nofollow">electrolyte decomposition pathways;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=LC-MS&option=203" rel="nofollow">LC-MS;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium ion battery&option=203" rel="nofollow">lithium ion battery;</a> </p> <div class="translation"> 机译：13C标记;电解质分解途径;LC-MS;锂离子电池; 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张薇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 张薇</a> <span> . 2017</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120110202532.html">锂离子电池电解质锂盐和电解液中酸度的检测方法</a> <b>[P]</b> . <span> 中国专利： CN107703138A </span> <span> . 2018-02-16</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061201773722.html">卤硅烷功能化碳酸酯电解质材料,其制备方法及在锂离子电池电解液中的应用</a> <b>[P]</b> . <span> 中国专利： CN102964372B </span> <span> . 2015.09.30</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130441604774.html">NONAQUEOUS ELECTROLYTE WHICH INHIBITS THE OXIDATION AND DECOMPOSITION OF ELECTROLYTE ON THE SURFACE OF POSITIVE ELECTRODE AND LITHIUM SECONDARY BATTERY CONTAINING THE ELECTROLYTE</a> <b>[P]</b> . <span> 外国专利：  KR20040080775A </span> <span> . 2004-09-20</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：抑制电解质在正电极和含有该电解质的锂二次电池表面上的氧化和分解的非电解质 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130413785555.html">LITHIUM TITANATE PARTICULATE POWDER AND PRODUCTION METHOD FOR SAME, MG-CONTAINING LITHIUM TITANATE PARTICULATE POWDER AND PRODUCTION METHOD FOR SAME, NEGATIVE ELECTRODE ACTIVE MATERIAL PARTICULATE POWDER FOR NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY, AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY</a> <b>[P]</b> . <span> 外国专利：  EP2612840A4 </span> <span> . 2016-07-20</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于非水电解质二次电池和非水电解质二次电池的含钛钛酸锂粉体及其生产方法，含MG的钛酸锂粉体及其生产方法，负极活性材料颗粒粉体 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130419415671.html">LITHIUM TITANATE PARTICULATE POWDER AND PRODUCTION METHOD FOR SAME, MG-CONTAINING LITHIUM TITANATE PARTICULATE POWDER AND PRODUCTION METHOD FOR SAME, NEGATIVE ELECTRODE ACTIVE MATERIAL PARTICULATE POWDER FOR NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY, AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY</a> <b>[P]</b> . <span> 外国专利：  KR20130097733A </span> <span> . 2013-09-03</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于非水电解质二次电池和非水电解质二次电池的含钛钛酸锂粉体及其生产方法，含MG的钛酸锂粉体及其生产方法，负极活性材料颗粒粉体 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> 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