Flexible and Washable Poly(Ionic Liquid) Nanofibrous Membrane with Moisture Proof Pressure Sensing for Real-Life Wearable Electronics

摘要

Real-life wearable electronics with long-term stable sensing performance are of significant practical interest to public. Wearable pressure sensors with washable, comfortable, breathable, and stable sensing ability are a key requirement to meet the desire. However, effects of ubiquitous ambient moisture and intrinsic defects of current capacitive sensing materials are two factors leading to unstable sensing performance of current pressure sensors. Existing ionic liquid-based materials (i.e., ionic hydrogel, ionic film, or ionic/elastomers composite) have been used for efficient capacitive pressure sensing but are highly sensitive and especially affected by moisture. In this work, we introduce a washable capacitive pressure-sensing textile based on the use of a hydrophobic poly(ionic liquid) nanofibrous membrane (PILNM) with good mechanical properties and satisfactory moisture proof sensing performance. The PILNM membranes possessing rich ions and microporous structures are novel ideal polymeric dielectric materials for amplification of signals with negligible stimulations. Moreover, the PILNMs exhibit very high stable sensing signals under moisture interference (up to 70% relative humidity) and repeated washings (more than 10 washings), especially suitable for wearable electronics. Notably, the PILNM-based wearable pressure-sensing textiles offer high sensitivity for low pressure and bent chord length changes with a low-pressure detection limit even under harsh deformations. Owing to the superior performance, the PILNM-based wearable pressure-sensing textiles are comfortable to wear and suitable for monitoring different human motions and pulse vibrations at various body positions. Meanwhile, the assembled multiple wearable pressure-sensing array can spatially map the contact area of the pressure stimuli and synchronously reflect finger movements.