Sr3GdLi(PO4)(3)F:Eu2+, Mn2+: A tunable blue-white color emitting phosphor via energy transfer for near-UV white LEDs

摘要

A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)(3)F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)(3)F phosphors have an efficient excitation in the range of 230-430 nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445 nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)(3)F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)(3)F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380 nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)(3)F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs.