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Enhancing the understanding of entropy through computation

机译:通过计算增强对熵的理解

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摘要

We devise an algorithm to enumerate the microstates of a system comprising N independent, distinguishable particles. The algorithm is applicable to a wide class of systems such as harmonic oscillators, free particles, spins, and other models for which there are no analytical solutions, for example, a system with single particle energy spectrum given by ε(p,q) = ε_0(p~2 + q~4), where p and q are non-negative integers. Our algorithm enables us to determine the approach to the limit N → ∞ within the microcanonical ensemble, and makes manifest the equivalence with the canonical ensemble. Various thermodynamic quantities as a function of N can be computed using our methods.
机译:我们设计一种算法来枚举包含N个独立的,可区分的粒子的系统的微状态。该算法适用于各种系统,例如谐波振荡器,自由粒子,自旋和其他没有解析解的模型,例如,具有ε(p,q)= ε_0(p〜2 + q〜4),其中p和q是非负整数。我们的算法使我们能够确定微规范集合中极限N→∞的方法,并证明与规范集合的等价性。可以使用我们的方法来计算作为N的函数的各种热力学量。

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