Compression behavior of soft PVC foams obtained by cardanol-derived plasticizer

摘要

This work is aimed to study the application of a bio-based plasticizer, obtained by acetylation and epoxydation of cardanol, for the production of soft PVC foams. The use of epoxidized cardanol acetate allowed obtaining a more efficient foaming of soft PVC compared to phthalate plasticizer bis(2-ethylhexyl) phthalate (DEHP), mainly due to the lower viscosity attained in the decomposition range of azodicarbonamide (AZDC). As a consequence, the foams produced by epoxidized cardanol acetate showed a lower density compared to those produced with DEHP. The lower density yielded lower values of compressive modulus. However, the modulus was shown to be not only dependent on the density, but also showed a direct dependence on the type of plasticizer used, in addition to processing temperature and AZDC content. As a consequence, the specific compressive modulus also showed a direct dependence on the type of plasticizer, processing temperature and AZDC content. Such dependence was explained by considering different cellular morphologies developed during foaming under different processing conditions, including type of plasticizer. In particular, it was shown that the lower viscosity attained by epoxidized cardanol acetate plasticized PVC involved an increase of the average pore size of the foam, which was shown to be the main cause of the variation of the specific compressive modulus.