Preparation of Co-MOF derived Co(OH)(2)/multiwalled carbon nanotubes as an efficient bifunctional electro catalyst for hydrazine and hydrogen peroxide detections

摘要

Metal-organic frameworks (MOFs) are the more desirable electrode materials in the recent development of electrocatalyts. Still, the electrocatalytic behavior as well as the stability of the prepared MOFs were diminished by its poor conductance. In this work, Cobalt hydroxide (Co (OH)(2)) functionalized multi walled carbon nanotubes (MWCNTs) with enhanced electro activity has been prepared using Co-based metal organic framework (Co MOF, ZIF-67) templates through room temperature electrochemical synthesis. The as synthesized composite has been utilized in the construction of MWCNTs-Co(OH)(2) modified glassy carbon electrode (GCE) for the determination of hydrazine (N2H4) and hydrogen peroxide (H2O2). The higher electrochemical performance of MWCNTs-Co(OH)(2)/GCE compared to individual MWCNTs/GCE and Co(OH)2/GCE was evident from the cyclic voltammetric studies. The characterizations of the composite have been carried out using various techniques. The electrochemical parameters such as linear range, limits of detection and sensitivity of MWCNTs-Co(OH)(2)/GCE were found to be more comparable with the previous N2H4 and H2O2 amperometric sensors reported in the literatures. The outcomes of practicability inspections were adequate with the recovery results of conventional methods. The high selectivity of MWCNTs-Co(OH)(2) modified GCE towards N2H4 and H2O2 has been further demonstrated in the presence of several biologically interfering molecules. (C) 2018 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.