Selective adsorption and degradation of organic pollutants over Au decorated Co doped titanate nanotubes under simulated solar light irradiation

摘要

Au decorated Co doped titanate nanotubes (TNT) was prepared for selective removal of methylene blue (MB) dye followed by selective photocatalytic degradation under solar light in presence of another highly concentrated dyes. The adsorption capacity of Co doped TNT was found to be increased with increasing Co content due to the increase in the number of pores and thus increase in surface area. Due to the high concentration of MB, Co doped TNT was completely covered by MB molecules and become difficult for light to Path though or absorbed by the Co doped TNT catalyst. In order to provide some photocatalytic characteristics for the catalyst, the doped TNTs were calcined to enhance the crystallinity and thus enhancing the photocatalytic activity, but the degradation rate was very low. Thus, another direction was started by reducing the adsorption ability of Co doped TNT through coating its surface by poly(allylamine hydrochloride), which changed the surface charge of the tubes to be positive and facilitate the electrostatic attachment of Au nanoparticles (15 nm). The synergetic effect of plasmonic Au nanoparticles in addition to adsorption and catalytic properties of Co doped TNT make the new composite promising catalyst for degradation of organic pollutants. It shows a good selectivity for adsorption and photocatalytic degradation of MB dye from dyes mixture. The obtained results indicate that Au decorated Co doped TNT will have a great effect on the development of selective environmental water treatment technologies specifically on flow challenges confronted by the wastewater treatment area. (C) 2018 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.